Difference between revisions of "Lindane"
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{{Definition|title= lindane | {{Definition|title= lindane | ||
| − | |definition=Lindane is the common name for the γ-isomer of hexachlorocyclohexane (HCH) and is used as an insecticide. | + | |definition=Lindane is the common name for the γ-isomer of hexachlorocyclohexane (HCH) and is used as an insecticide. Like all isomers of HCH, lindane belongs to the greater group of [[organochlorine compounds]]. |
<ref name = OECD>[http://www.ospar.org/documents%5Cdbase%5Cpublications%5Cp00153_Background%20document%20on%20lindane%20updated.pdf OECD OSPAR Commission, 2006: OSPAR background document on lindane]</ref>}} | <ref name = OECD>[http://www.ospar.org/documents%5Cdbase%5Cpublications%5Cp00153_Background%20document%20on%20lindane%20updated.pdf OECD OSPAR Commission, 2006: OSPAR background document on lindane]</ref>}} | ||
== Notes == | == Notes == | ||
| − | The use of HCH is generally prohibited in Western Europe and North America since 1979. The use of its main constituent, lindane has been phased out in Europe since 2002. Lindane is an insecticide which had a widespread use in agriculture and forestry, for seed treatment, in household biocidal products, as a textile preservative and as a wood preservative. Lindane has been intensively used for many years since 1949 but has been replaced in most applications. From an estimated use of nearly 7900 tonnes in 1970 in Europe, the use decreased to about 2300 tonnes in 1996. | + | The use of HCH is generally prohibited in Western Europe and North America since 1979. The use of its main constituent, lindane has been phased out in Europe since 2002. Lindane is an insecticide which had a widespread use in agriculture and forestry, for seed treatment, in household biocidal products, as a textile preservative and as a wood preservative. Lindane has been intensively used for many years since 1949 but has been replaced in most applications. From an estimated use of nearly 7900 tonnes in 1970 in Europe, the use decreased to about 2300 tonnes in 1996.<ref name = OECD>[http://www.ospar.org/documents%5Cdbase%5Cpublications%5Cp00153_Background%20document%20on%20lindane%20updated.pdf OECD OSPAR Commission, 2006: OSPAR background document on lindane]</ref> |
| − | |||
| + | Lindane is a relatively volatile substance, therefore high amounts (hundreds of tonnes each year) of it entered the atmosphere. This atmospheric load gets partly deposited in the ocean. Another major input of lindane to the marine environment is riverine transport from the application areas. Lindane is more water soluble than most other organochlorine compounds, which causes it to be less [[adsorption|adsorbed]] to particles. | ||
| + | Lindane is very stable in water, it is mainly removed by adsorption to sediments and uptake by [[biota]], where some biodegradation may take place. It may take between 20 and 200 days to half the lindane concentration of sea water. Although lindane is less lipophilic than other organochlorine compounds it also has a tendency towards [[bioaccumulation]]. It also has some potential to [[biomagnification|biomagnify]]. It proses a greater threat to [[pollution and marine mammals|marine mammals]] than to [[pollution and pelagic fishes|predatory fishes]] because marine mammals seam to be less efficient in eliminating them from their bodies. Fish appear to be able to eliminate lindane through their gills. | ||
| + | The global marine background concentration of lindane has been estimated to be 0,6 ng/l. It occurs word wide and is present in all compartments and trophic levels of the arctic. Concentrations in the North Sea range from 0,3 to 8 ng/l (in the Dutch Wadden Sea). Concentrations of lindane in biota are thought to be decreasing. They have been as up to a few µg/kg [[wet weight]] in [[pollution and zoobenthos|mussels]], 152 µg/kg [[wet weight]] in fish, and 2-4 mg/kg [[lipid weight]] in the [[blubber ]] of marine mammals. | ||
| + | Water concentrations between 0,5 µg/l and 2,5 µg/l have proved lethal for fish, shrimp and crabs. Zooplankton such as Daphnia appears to be able to tolerate concentrations up to 1600 µg/l.<ref name = OECD>[http://www.ospar.org/documents%5Cdbase%5Cpublications%5Cp00153_Background%20document%20on%20lindane%20updated.pdf OECD OSPAR Commission, 2006: OSPAR background document on lindane]</ref> | ||
| + | <P> | ||
| + | <BR> | ||
| + | <P> | ||
| − | + | == Environmental standards and legislation == | |
| − | + | ||
| − | + | [[OSPAR List of priority substances|Included in the OSPAR list of substances of priority action (as hexachlorocyclohexane)]] | |
| − | + | <P> | |
| − | + | <BR> | |
| − | + | <P> | |
| − | + | ||
| − | + | == See also == | |
| + | |||
| + | [[http://www.ospar.org/documents%5Cdbase%5Cpublications%5Cp00153_Background%20document%20on%20lindane%20updated.pdf OSPAR background document on lindane] | ||
| + | <P> | ||
| + | <BR> | ||
| + | <P> | ||
| + | ==References== | ||
| + | <references/> | ||
| + | |||
| + | [[Category:Coastal and marine pollution]] | ||
Revision as of 10:26, 6 August 2009
Definition of lindane:
Lindane is the common name for the γ-isomer of hexachlorocyclohexane (HCH) and is used as an insecticide. Like all isomers of HCH, lindane belongs to the greater group of organochlorine compounds.
[1]
This is the common definition for lindane, other definitions can be discussed in the article
|
Notes
The use of HCH is generally prohibited in Western Europe and North America since 1979. The use of its main constituent, lindane has been phased out in Europe since 2002. Lindane is an insecticide which had a widespread use in agriculture and forestry, for seed treatment, in household biocidal products, as a textile preservative and as a wood preservative. Lindane has been intensively used for many years since 1949 but has been replaced in most applications. From an estimated use of nearly 7900 tonnes in 1970 in Europe, the use decreased to about 2300 tonnes in 1996.[1]
Lindane is a relatively volatile substance, therefore high amounts (hundreds of tonnes each year) of it entered the atmosphere. This atmospheric load gets partly deposited in the ocean. Another major input of lindane to the marine environment is riverine transport from the application areas. Lindane is more water soluble than most other organochlorine compounds, which causes it to be less adsorbed to particles.
Lindane is very stable in water, it is mainly removed by adsorption to sediments and uptake by biota, where some biodegradation may take place. It may take between 20 and 200 days to half the lindane concentration of sea water. Although lindane is less lipophilic than other organochlorine compounds it also has a tendency towards bioaccumulation. It also has some potential to biomagnify. It proses a greater threat to marine mammals than to predatory fishes because marine mammals seam to be less efficient in eliminating them from their bodies. Fish appear to be able to eliminate lindane through their gills.
The global marine background concentration of lindane has been estimated to be 0,6 ng/l. It occurs word wide and is present in all compartments and trophic levels of the arctic. Concentrations in the North Sea range from 0,3 to 8 ng/l (in the Dutch Wadden Sea). Concentrations of lindane in biota are thought to be decreasing. They have been as up to a few µg/kg wet weight in mussels, 152 µg/kg wet weight in fish, and 2-4 mg/kg lipid weight in the blubber of marine mammals.
Water concentrations between 0,5 µg/l and 2,5 µg/l have proved lethal for fish, shrimp and crabs. Zooplankton such as Daphnia appears to be able to tolerate concentrations up to 1600 µg/l.[1]
Environmental standards and legislation
Included in the OSPAR list of substances of priority action (as hexachlorocyclohexane)
See also
[OSPAR background document on lindane
