Difference between revisions of "Glyphosate"

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(New page: Introduced in 1973. Today it is used in Roundup WeatherMax, Roundup UltraMax and other non selective herbicides. is among the worlds most widely used herbicides, Used in 130 countries for ...)
 
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Introduced in 1973. Today it is used in Roundup WeatherMax, Roundup UltraMax and other non selective herbicides. is among the worlds most widely used herbicides, Used in 130 countries for weed control in more than 100 crops
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{{Definition|title=glyphosate
  
The technical isopropylamine salt (IPA) is
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|definition=Glyphosate was first used as a herbicide in 1973. Today it's used in Roundup WeatherMax, Roundup UltraMax and other non selective herbicides. It is among the worlds most widely used herbicides, is used in 130 countries for weed control of more than 100 crops. <ref>[http://www.monsanto.com/monsanto/content/products/productivity/roundup/back_history.pdf Monsanto 2005 History of Monsanto's Glyphosate Herbicides]</ref> It occurs as a white crystalline solid. <ref name="Epa">[http://www.epa.gov/oppsrrd1/REDs/old_reds/glyphosate.pdf EPA 1993 Registration Eligibility Decision for Glyphosate ]</ref> }}
a white crystalline solid with a melting point of 200EC and a bulk density of 1.74
 
lb/ft3. It is 1% soluble in water at 25EC and insoluble in ethanol, acetone, or
 
benzene. The technical sodium salt is a white crystalline solid which decomposes
 
at 140EC with a bulk density of 30 lb/ft3.
 
  
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== Notes ==
  
The isopropylamine salt of glyphosate, the active ingredient in 53 of these registrations, is used as
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{| class="toccolours" border="1" style="float: right; clear: right; margin: 0 0 1em 1em; border-collapse: collapse;"
a herbicide to control a number of broadleaf weeds and grasses. The principal food use sites
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! bgcolor="#FF8888" | Alachlor
include corn, wheat, sorghum, citrus and stone fruits, potatoes and onions, asparagus, coffee,
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|-
peanuts, and pineapples. There are also a number of non-food use sites including
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| align="center" bgcolor="#FFFFFF" | [[Image:Alachlor.png|200px|Alachlor]]
ornamental, turf, forestry, and industrial rights-of-way.
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|-
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! bgcolor="#8888FF" | Formula
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|-
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| align="center" | C<sub>14</sub>H<sub>20</sub>ClNO<sub>2</sub>
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|-
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|}
  
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The glyphosate is used as a herbicide to control a number of broadleaf weeds and grasses. The principal food use sites
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include corn, wheat, sorghum, citrus and stone fruits, potatoes and onions, asparagus, coffee, peanuts, and pineapples. There are also a number of non-food use sites including ornamental, turf, forestry, and industrial rights-of-way (rail road tracks).<ref name="Epa">[http://www.epa.gov/oppsrrd1/REDs/old_reds/glyphosate.pdf EPA 1993 Registration Eligibility Decision for Glyphosate ]</ref>
  
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Although it is rather soluble in water (11,6 g/l), in application sites, glyphosate adsorbs to soils and should stay in the top 15 cm of soils. This reduces its exposure to surface waters and the marine environment. It is a rather unstable molecule that can be biodegraded. In most environments, it usually takes less than 30 days to halve its concentration, although it can in some cases take up to 174 days. Glyphosate is usually biodegraded to [[AMPA]].<ref name="Epa">[http://www.epa.gov/oppsrrd1/REDs/old_reds/glyphosate.pdf EPA 1993 Registration Eligibility Decision for Glyphosate ]</ref>
  
It is a rather stable molecule but can be easily biodegraded. In most environments, it takes less than 30 days to halve its concentration. The mayor metabolite is [[AMPA]]
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Glyphosate doesn't have a tendency to [[bioaccumulation|bioaccumulate]] or [[biomagnification|biomagnify]].<ref name="Epa">[http://www.epa.gov/oppsrrd1/REDs/old_reds/glyphosate.pdf EPA 1993 Registration Eligibility Decision for Glyphosate ]</ref>
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Concentrations of 10µg/l might cause acute toxicity in one water flea species, while other zooplankton can tolerate concentrations up to or above 25 mg/l.  Some fish species start dying at concentrations above 5 mg/l while others like goldfish might even tolerate concentrations above 19 g/l. <ref>[http://www.pesticideinfo.org/Detail_Chemical.jsp?Rec_Id=PC33138 www.pesticideinfo.org 25 August 2009]</ref>
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Concentrations in fresh surface water range between 0.5 and 1700 µg/l. <ref>[http://www.inchem.org/documents/ehc/ehc/ehc159 www.inchem.org 25 August 2009]</ref>
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<P>
 +
<BR>
 +
<P>
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== Environmental standards and legislation ==
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[[List of priority substances|Included in the water framework list of priority substances]]
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<P>
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<BR>
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<P>
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== See also ==
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[http://www.vliz.be/projects/endis/EDnorth.php?showchemprop=true&showeffects=true&chemeffects=true&chemid=457 Glyphosate on ED North Database]
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<P>
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<BR>
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<P>
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==References==
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<references/>
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[[Category:Coastal and marine pollution]]

Revision as of 11:29, 25 August 2009

Definition of glyphosate:
Glyphosate was first used as a herbicide in 1973. Today it's used in Roundup WeatherMax, Roundup UltraMax and other non selective herbicides. It is among the worlds most widely used herbicides, is used in 130 countries for weed control of more than 100 crops. [1] It occurs as a white crystalline solid. [2]
This is the common definition for glyphosate, other definitions can be discussed in the article

Notes

Alachlor
Alachlor
Formula
C14H20ClNO2

The glyphosate is used as a herbicide to control a number of broadleaf weeds and grasses. The principal food use sites include corn, wheat, sorghum, citrus and stone fruits, potatoes and onions, asparagus, coffee, peanuts, and pineapples. There are also a number of non-food use sites including ornamental, turf, forestry, and industrial rights-of-way (rail road tracks).[2]

Although it is rather soluble in water (11,6 g/l), in application sites, glyphosate adsorbs to soils and should stay in the top 15 cm of soils. This reduces its exposure to surface waters and the marine environment. It is a rather unstable molecule that can be biodegraded. In most environments, it usually takes less than 30 days to halve its concentration, although it can in some cases take up to 174 days. Glyphosate is usually biodegraded to AMPA.[2]

Glyphosate doesn't have a tendency to bioaccumulate or biomagnify.[2]

Concentrations of 10µg/l might cause acute toxicity in one water flea species, while other zooplankton can tolerate concentrations up to or above 25 mg/l. Some fish species start dying at concentrations above 5 mg/l while others like goldfish might even tolerate concentrations above 19 g/l. [3]


Concentrations in fresh surface water range between 0.5 and 1700 µg/l. [4]


Environmental standards and legislation

Included in the water framework list of priority substances


See also

Glyphosate on ED North Database


References